Question: 39: On heating blue coloured powder of copper (II) nitrate in a boiling tube, copper oxide (black), oxygen gas and a brown gas X is formed
(a) Write a balanced chemical equation of the reaction.
(b) Identify the brown gas X evolved.
(c) Identify the type of reaction.
(d) What could be the pH range of aqueous solution of the gas X?
The brown gas so formed in this reaction is nitrogen dioxide.
(b) Thus, the brown gas ‘X’ is nitrogen dioxide.
(c) This is a Decomposition reaction
(d) Nitrogen dioxide forms nitric acid when reacts with water. The pH value of an acid is less than 7 to 0. Thus the pH range of the aqueous solution of gas ‘X’ i.e. Nitrogen dioxide many be from 0 to less than 7.
The reaction between nitrogen dioxide and water can be written as follows:-
Question:40. Give the characteristic tests for the following gases:-
(a) Carbon dioxide turns lime water milky as it forms calcium carbonate with lime water. This is the characteristics test for carbon dioxide.
(b) The smell of sulphur dioxide gas is like burning of sulphur, which is the characteristics test for sulphur dioxide. Sulhpur dioxide turns moist litmus paper from blue to red.
(c) When a burnt candle or match stick is brought near the oxygen gas, it starts burning brightly. This is the characteristic test for oxygen gas.
(d) When a burnt candle or match stick, it burns with pop sound, which is the characteristic test for hydrogen gas.
Question:41. What happens when a piece of
(a) zinc metal is added to copper sulphate solution?
(b) aluminium metal is added to dilute hydrochloric acid?
(c) silver metal is added to copper sulphate solution?
Also, write the balanced chemical equation if the reaction occurs
(a) Zinc sulphate and copper is formed when zinc reacts with copper sulphate.
(b) Hydrochloric acid forms aluminium chloride and hydrogen gas when reacts with aluminium metal.
(c) When silver metal is added to copper sulphate solution, no reaction takes place because silver is less reactive than copper.
42. What happens when zinc granules are treated with dilute solution of H2SO4, HCl, HNO3, NaCl and NaOH, also write the chemical equations if reaction occurs.
Hydrogen gas and zinc sulphate are formed when zinc granules are treated with sulphuric acid.
Zinc chloride and hydrogen gas are formed, when zinc granules are treated with hydrochloric acid.
Similarly, hydrogen gas and zinc nitrate are formed when zinc granules are treated with nitric acid.
Since, zinc is less reactive than sodium, thus no reaction takes place when zinc granules are treated with sodium chloride.
Sodium zincate and hydrogen gas are formed when zinc granules are treated with sodium hydroxide and water.
43. On adding a drop of barium chloride solution to an aqueous solution of sodium sulphite, white precipitate is obtained.
(a) Write a balanced chemical equation of the reaction involved
(b) What other name can be given to this precipitation reaction?
(c) On adding dilute hydrochloric acid to the reaction mixture, white precipitate disappears. Why?
(a) A white precipitate of barium sulphite is formed when barium chloride is added to the solution o sodium sulphite.
(b) This precipitation reaction is also a double displacement reaction.
(c) Barium chloride, suphur dioxide and water are formed hen dilute hydrochloric acid is added to this solution of barium sulphete and sodium chloride. Since barium chloride is a soluble substance, thus white precipitate of barium sulphite disappears.
44. You are provided with two containers made up of copper and aluminium. You are also provided with solutions of dilute HCl, dilute HNO3, ZnCl2 and H2O. In which of the above containers these solutions can be kept?
The solution of dilute HCl, dilute HNO3, ZnCl2 and H2O can be kept in the container made of copper instead of aluminium. Since copper is a noble metal and does not react with HCl, HNO3 while these react with aluminium.
Thus container made of copper would be suitable to keep the given solutions instead of aluminium.
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